Functionalized Carbazolyl Hydro‐ and Allyl‐Silanes
Hädinger, Pauline 1; Hinz, Alexander
1
1 Institut für Anorganische Chemie (AOC), Karlsruher Institut für Technologie (KIT)
11 Institut für Anorganische Chemie (AOC), Karlsruher Institut für Technologie (KIT)
Abstract:
The synthesis and properties of silanes bearing a bulky carbazolyl substituent are described. Metathesis routes with different reagents under different conditions are required to obtain the compounds of the general formula RSi(X)$_{2}$H and RSi(X)$_{2}$All (X=Cl, N$_{3}$, NCO, NCS, NH$_{2}$, All=CH$_{2}$CHCH$_{2}$). The silanes were studied by XRD, NMR and IR spectroscopy and all findings were corroborated by DFT methods.
| Zugehörige Institution(en) am KIT | Institut für Anorganische Chemie (AOC) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsjahr | 2022 |
| Sprache | Englisch |
| Identifikator | ISSN: 1434-1948, 1099-0682 KITopen-ID: 1000143226 |
| Erschienen in | European journal of inorganic chemistry |
| Verlag | Wiley-VCH Verlag |
| Band | 2022 |
| Heft | 11 |
| Seiten | e202101112 |
| Vorab online veröffentlicht am | 09.02.2022 |
| Nachgewiesen in | Scopus Dimensions Web of Science |