Autoxidation of 4-Hydrazinylquinolin-2(1H)-one; Synthesis of Pyridazino[4,3-c:5,6-c′ ]diquinoline-6,7(5H,8H)-diones
Abstract:
An efficient synthesis of a series of pyridazino[4,3-c:5,6-c′]diquinolines was achieved via the autoxidation of 4-hydrazinylquinolin-2(1H)-ones. IR, NMR ($^1$H and $^13$C), mass spectral data, and elemental analysis were used to fit and elucidate the structures of the newly synthesized compounds. X-ray structure analysis and theoretical calculations unequivocally proved the formation of the structure. The possible mechanism for the reaction is also discussed.
| Zugehörige Institution(en) am KIT | Institut für Biologische und Chemische Systeme (IBCS) Institut für Organische Chemie (IOC) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsjahr | 2022 |
| Sprache | Englisch |
| Identifikator | ISSN: 1420-3049 KITopen-ID: 1000145745 |
| HGF-Programm | 43.33.11 (POF IV, LK 01) Adaptive and Bioinstructive Materials Systems |
| Erschienen in | Molecules |
| Verlag | MDPI |
| Band | 27 |
| Heft | 7 |
| Seiten | Art.-Nr.: 2125 |
| Bemerkung zur Veröffentlichung | Gefördert durch den KIT-Publikationsfonds |
| Vorab online veröffentlicht am | 25.03.2022 |
| Schlagwörter | 4-hydrazinylquinolin-2(1H)-one; pyridazino[4,3-c:5,6-c′]diquinoline-6,7(5H,8H)-dione; autoxidation reaction; X-ray; DFT |
| Nachgewiesen in | Dimensions Web of Science Scopus |