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Oxide‐Based Solid‐State Batteries: A Perspective on Composite Cathode Architecture

Ren, Yaoyu; Danner, Timo; Moy, Alexandra; Finsterbusch, M.; Finsterbusch, Martin; Hamann, Tanner; Dippell, Jan; Fuchs, Till; Müller, Marius 1; Hoft, Ricky; Weber, André ORCID iD icon 1; Curtiss, Larry A.; Zapol, Peter; Klenk, Matthew; Ngo, Anh T.; Barai, Pallab; Wood, Brandon C.; Shi, Rongpei; Wan, Liwen F.; ... mehr

Abstract:

The garnet-type phase Li$_7$La$_3$Zr$_2$O$_{12}$ (LLZO) attracts significant attention as an oxide solid electrolyte to enable safe and robust solid-state batteries (SSBs) with potentially high energy density. However, while significant progress has been made in demonstrating compatibility with Li metal, integrating LLZO into composite cathodes remains a challenge. The current perspective focuses on the critical issues that need to be addressed to achieve the ultimate goal of an all-solid-state LLZO-based battery that delivers safety, durability, and pack-level performance characteristics that are unobtainable with state-of-the-art Li-ion batteries. This perspective complements existing reviews of solid/solid interfaces with more emphasis on understanding numerous homo- and heteroionic interfaces in a pure oxide-based SSB and the various phenomena that accompany the evolution of the chemical, electrochemical, structural, morphological, and mechanical properties of those interfaces during processing and operation. Finally, the insights gained from a comprehensive literature survey of LLZO–cathode interfaces are used to guide efforts for the development of LLZO-based SSBs.


Verlagsausgabe §
DOI: 10.5445/IR/1000153287
Veröffentlicht am 02.12.2022
Originalveröffentlichung
DOI: 10.1002/aenm.202201939
Scopus
Zitationen: 57
Web of Science
Zitationen: 56
Dimensions
Zitationen: 59
Cover der Publikation
Zugehörige Institution(en) am KIT Center for Electrochemical Energy Storage Ulm & Karlsruhe (CELEST)
Institut für Angewandte Materialien – Elektrochemische Technologien (IAM-ET1)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2022
Sprache Englisch
Identifikator ISSN: 1614-6832, 1614-6840
KITopen-ID: 1000153287
Erschienen in Advanced Energy Materials
Verlag Wiley-VCH Verlag
Band 13
Heft 1
Seiten Art.-Nr.: 2201939
Vorab online veröffentlicht am 20.11.2022
Schlagwörter ceramic cathode/electrolyte interface, grain boundaries, oxide solid electrolyte, solid state battery
Nachgewiesen in Scopus
Dimensions
Web of Science
Globale Ziele für nachhaltige Entwicklung Ziel 7 – Bezahlbare und saubere Energie
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