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Nitrogen‐Containing Polymers Derived from Terpenes: Possibilities and Limitations

Scheelje, Frieda Clara M. 1; Destaso, Francesca C. C. 2; Cramail, Henri; Meier, Michael A. R. 1,2
1 Institut für Organische Chemie (IOC), Karlsruher Institut für Technologie (KIT)
2 Institut für Biologische und Chemische Systeme (IBCS), Karlsruher Institut für Technologie (KIT)

Abstract:

Nitrogen-containing polymers are widely applied materials, including polyamides, polyurethanes, and polyureas as well as epoxy thermosets. Their indispensability and the urgent need to replace fossil-based polymers considering more sustainable alternatives lead to significant efforts in exploring renewable feedstock as potential new building blocks. Being obtained from non-edible plant parts and often occurring as waste products, terpenes represent a promising group of renewable compounds that are of possible interest in the synthesis of nitrogen-containing polymers. The structural diversity of terpenes in combination with the mechanical properties that nitrogen-containing moieties bring into polymers can give rise to novel biobased materials that outstand mechanical and thermal properties of conventional fossil-based counterparts. In this review, an overview of the use of terpene compounds in the synthesis of nitrogen-containing polymers is given, covering different approaches to make use of terpenes as a valuable pool of renewable monomers.


Verlagsausgabe §
DOI: 10.5445/IR/1000154480
Veröffentlicht am 13.01.2023
Originalveröffentlichung
DOI: 10.1002/macp.202200403
Scopus
Zitationen: 4
Dimensions
Zitationen: 5
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Biologische und Chemische Systeme (IBCS)
Institut für Organische Chemie (IOC)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2022
Sprache Englisch
Identifikator ISSN: 1022-1352, 0025-116X, 1521-3935
KITopen-ID: 1000154480
HGF-Programm 43.33.11 (POF IV, LK 01) Adaptive and Bioinstructive Materials Systems
Erschienen in Macromolecular Chemistry and Physics
Verlag Wiley-VCH Verlag
Band 224
Heft 3
Seiten Art.-Nr.: 2200403
Vorab online veröffentlicht am 05.12.2022
Schlagwörter amines, biobased polymers, epoxy-amine resins, polyamides, polyurethanes, sustainability, terpenes
Nachgewiesen in Web of Science
Dimensions
Scopus
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