Suppressing the aromatic cycle of the dimethyl ether to hydrocarbons reaction on zeolites

The influence of the zeolite framework type on the conversion of dimethyl ether (DME) to hydrocarbons (DTH) was investigated for *MRE, MFI and TON zeolite catalysts. Remarkable differences in the catalytic performance of the materials were observed. In particular, the *MRE zeolite showed an exceptionally high yield of olefins (90%) with a substantial ratio of products in the chain length range C$_5$-C$_{11}$. Additionally, the longevity of the *MRE zeolite clearly exceeded previously reported data. The comparison of mechanistic parameters (Hydrogen-Transfer-Index HTI$_{Ci}$ and C$_3$/C$_2$ ratio) demonstrated for this zeolite, that the formation of aromatics in the reaction network can be almost completely suppressed under suitable reaction conditions. By varying the reaction parameters temperature, DME partial pressure and weight hourly space velocity (WHSV), it was possible to identify the optimal combination of selectivity and deactivation resistance for each material. The olefin-rich DTH product of the *MRE zeolite offers manifold possibilities for further conversion to valuable renewably produced low-emission fuels like gasoline or jet fuel.