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Transition Metal Complexes of Thiosemicarbazides, Thiocarbohydrazides, and Their Corresponding Carbazones with Cu(I), Cu(II), Co(II), Ni(II), Pd(II), and Ag(I)—A Review

Aly, Ashraf A. ; Abdallah, Elham M.; Ahmed, Salwa A.; Rabee, Mai M.; Bräse, Stefan 1
1 Institut für Biologische und Chemische Systeme (IBCS), Karlsruher Institut für Technologie (KIT)

Abstract:

This review focuses on some interesting and recent applications of transition metals towards the complexation of thiosemicarbazides, thiocarbohydrazides, and their corresponding carbazones. We started the review with a description of the chosen five metals, including Cu[Cu(I), Cu(II], Co(II), Ni(II), Pd(II), and Ag(I) and their electronic configurations. The stability of the assigned complexes was also discussed. We shed light on different routes describing the synthesis of these ligands. We also reported on different examples of the synthesis of Cu(I), Cu(II), Co(II), Ni(II), Ag(I), and Pd(II) of thiosemicarbazide and thiocarbohydrazide complexes (until 2022). This review also deals with a summary of the fruitful use of metal complexes of thiosemicarbazones and thiocarbazones ligands in the field of catalysis. Finally, this recent review focuses on the applications of these complexes related to their biological importance.


Verlagsausgabe §
DOI: 10.5445/IR/1000156976
Veröffentlicht am 16.03.2023
Originalveröffentlichung
DOI: 10.3390/molecules28041808
Scopus
Zitationen: 13
Web of Science
Zitationen: 12
Dimensions
Zitationen: 13
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Biologische und Chemische Systeme (IBCS)
Institut für Organische Chemie (IOC)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2023
Sprache Englisch
Identifikator ISSN: 1420-3049
KITopen-ID: 1000156976
HGF-Programm 43.33.11 (POF IV, LK 01) Adaptive and Bioinstructive Materials Systems
Erschienen in Molecules
Verlag MDPI
Band 28
Heft 4
Seiten Art.-Nr.: 1808
Bemerkung zur Veröffentlichung Gefördert durch den KIT-Publikationsfonds
Vorab online veröffentlicht am 14.02.2023
Schlagwörter thiosemicarbazides; thiosemicarbazones; synthesis; Cu(I); Cu(II); Co(II); Ni(II); Pd(II) and Ag(I) complexes; biological activity; catalysis
Nachgewiesen in Scopus
Web of Science
Dimensions
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