Multi compression–expansion process for chemical energy conversion: Transformation of methane to unsaturated hydrocarbons and hydrogen

With the global energy system moving towards renewable energies, there is an increasing demand for flexible conversion processes which can cope with the temporally and locally fluctuating nature of energy supply and energy demand. Promising candidate processes are based on coupled chemical/energy conversion. In this work, the pyrolytic conversion of methane to valuable high-energy content substances like hydrogen and unsaturated hydrocarbons by the compression/expansion process of a piston engine is investigated. In particular, the potential of running this conversion in a multi-compression–expansion (MCE) mode where a gas sample is subject to multiple compression–expansion strokes, is assessed. The methane conversion and target species yields of this multi-compression mode relative to a single compression–expansion mode are assessed. Experimental studies with a rapid compression–expansion machine are used for this. The experiments are complemented by numerical simulations, which help to interpret the experimental findings. We found that both conversion and target species yields can be increased significantly by the multi-compression–expansion processes relative to a single compression–expansion. ... mehrFor instance, at typical engine operation conditions, ten compression–expansion cycles increase the methane conversion by a factor of three to four (from approx. 15 % to 68 %), the hydrogen yield by a factor of five, and the unsaturated hydrocarbon yields by a factor of three, compared to a single compression–expansion process. The results encourage considering a new role for piston-engines as work-to-chemical energy converters, in addition to their conventional heat-engine (chemical energy to work) operation.