An organic cage controlling the dimension and stability of gold nanoparticles
Abstract:
A molecular cage encapsulating gold nanoparticles is presented. Six benzylic thioethers are pointing into its cavity, stabilizing the particles in a 1 : 1 ligand-to-particle-ratio in excellent yields. They are bench-stable for several months and can withstand unprecedented thermal stress of up to 130 °C, documenting the advantages of the cage-type stabilization over open-chain analogues.
| Zugehörige Institution(en) am KIT | Institut für Nanotechnologie (INT) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsjahr | 2023 |
| Sprache | Englisch |
| Identifikator | ISSN: 1359-7345, 0022-4936, 0009-241X, 1364-548X, 2050-5620, 2050-5639 KITopen-ID: 1000158003 |
| HGF-Programm | 43.32.01 (POF IV, LK 01) Molecular Materials Basis for Optics & Photonics |
| Erschienen in | Chemical Communications |
| Verlag | Royal Society of Chemistry (RSC) |
| Band | 59 |
| Heft | 33 |
| Seiten | 4895-4898 |
| Nachgewiesen in | Dimensions Scopus OpenAlex Web of Science |