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Improved Route to Linear Triblock Copolymers by Coupling with Glycidyl Ether-Activated Poly(ethylene oxide) Chains

Krause, Daniel T.; Krämer, Susanna; Siozios, Vassilios; Butzelaar, Andreas J. 1; Dulle, Martin; Förster, Beate; Theato, Patrick ORCID iD icon 1,2; Mayer, Joachim 1; Winter, Martin; Förster, Stephan; Wiemhöfer, Hans-Dieter; Grünebaum, Mariano
1 Institut für Technische Chemie und Polymerchemie (ITCP), Karlsruher Institut für Technologie (KIT)
2 Institut für Biologische Grenzflächen (IBG), Karlsruher Institut für Technologie (KIT)

Abstract:

Poly(ethylene oxide) block copolymers (PEOz BCP) have been demonstrated to exhibit remarkably high lithium ion (Li+) conductivity for Li+ batteries applications. For linear poly(isoprene)-b-poly(styrene)-b-poly(ethylene oxide) triblock copolymers (PIxPSyPEOz), a pronounced maximum ion conductivity was reported for short PEOz molecular weights around 2 kg mol1. To later enable a systematic exploration of the influence of the PIx and PSy block lengths and related morphologies on the ion conductivity, a synthetic method is needed where the short PEOz block length can be kept constant, while the PIx and PSy block lengths could be systematically and independently varied. Here, we introduce a glycidyl ether route that allows covalent attachment of pre-synthesized glycidyl-end functionalized PEOz chains to terminate PIxPSy BCPs. The attachment proceeds to full conversion in a simplified and reproducible one-pot polymerization such that PIxPSyPEOz with narrow chain length distribution and a fixed PEOz block length of z = 1.9 kg mol1 and a Đ = 1.03 are obtained. The successful quantitative end group modification of the PEOz block was verified by nuclear magnetic resonance (NMR) spectroscopy, gel permeation chromatography (GPC) and differential scanning calorimetry (DSC). ... mehr

Zugehörige Institution(en) am KIT Institut für Technische Chemie und Polymerchemie (ITCP)
Publikationstyp Zeitschriftenaufsatz
Publikationsmonat/-jahr 05.2023
Sprache Englisch
Identifikator ISSN: 2073-4360
KITopen-ID: 1000159101
HGF-Programm 43.33.11 (POF IV, LK 01) Adaptive and Bioinstructive Materials Systems
Weitere HGF-Programme 43.32.01 (POF IV, LK 01) Molecular Materials Basis for Optics & Photonics
Erschienen in Polymers
Verlag MDPI
Band 15
Heft 9
Seiten Art.-Nr.: 2128
Vorab online veröffentlicht am 29.04.2023
Schlagwörter polymers, block copolymers, polyethylene oxide (PEO), convergent synthesis, epoxide, anionic polymerization, microphase separation, morphology
Nachgewiesen in Web of Science
OpenAlex
Scopus
Dimensions
Globale Ziele für nachhaltige Entwicklung Ziel 7 – Bezahlbare und saubere Energie

Verlagsausgabe §
DOI: 10.5445/IR/1000159101
Veröffentlicht am 06.07.2023
Originalveröffentlichung
DOI: 10.3390/polym15092128
Scopus
Zitationen: 2
Web of Science
Zitationen: 2
Dimensions
Zitationen: 2
Seitenaufrufe: 62
seit 06.07.2023
Downloads: 32
seit 12.07.2023
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