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Localised degradation within sulfide-based all-solid-state electrodes visualised by Raman mapping

Lim, Jungwoo; Zhou, Yundong; Powell, Rory H.; Ates, Tugce 1; Passerini, Stefano 1; Hardwick, Laurence J.
1 Helmholtz-Institut Ulm (HIU), Karlsruher Institut für Technologie (KIT)

Abstract:

The distribution of degradation products, before and after cycling, within common sulfide-based solid electrolytes (β-Li$_3$PS$_4$, Li$_6$PS$_5$Cl and Li$_{10}$GeP$_2$S$_{12}$) was mapped using Raman microscopy. All composite electrodes displayed the appearance of side reaction products after the initial charge-discharge cycle, located at the site of a LiNi$_{0.6}$Mn$_{0.2}$Co$_{0.2}$O$_2$ particle.


Verlagsausgabe §
DOI: 10.5445/IR/1000160195
Veröffentlicht am 05.07.2023
Cover der Publikation
Zugehörige Institution(en) am KIT Helmholtz-Institut Ulm (HIU)
Publikationstyp Zeitschriftenaufsatz
Publikationsdatum 22.06.2023
Sprache Englisch
Identifikator ISSN: 1359-7345, 1364-548X
KITopen-ID: 1000160195
HGF-Programm 38.02.01 (POF IV, LK 01) Fundamentals and Materials
Erschienen in Chemical Communications
Verlag Royal Society of Chemistry (RSC)
Band 59
Heft 51
Seiten 7982–7985
Nachgewiesen in Web of Science
Dimensions
Scopus
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