Co-Hydroprocessing of Fossil Middle Distillate and Bio-Derived Durene-Rich Heavy Ends under Hydrotreating Conditions

Methanol-to-gasoline (MTG) and dimethyl ether-to-gasoline (DTG), as industrially approved processes for producing greenhouse gas-neutral gasoline, yield byproducts rich in heavy mono-ring aromatics such as 1,2,4,5-tetramethylbenzene (durene). Due to its tendency to crystallize and the overall poor fuel performance, the heavy fuel fraction is usually further processed using aftertreatment units designed for this purpose. This research article discusses the co-hydroprocessing (HP) of bio-derived heavy gasoline (HG) with fossil middle distillate (MD), drawing on available refinery hydrotreaters. Co-HP experiments were conducted in a laboratory-scale fixed bed reactor using an industrial CoMo/g-Al2O3 catalyst, varying the space-time between 0.7 and 4.0 cm3
Cat h cm􀀀3 Feed and the reaction temperature between 340 and 390 °C. In addition to the durene conversion, special attention was paid to the octane and cetane numbers (CN) of gasoline and MD, respectively. A six-lump model with ten parameters was developed to predict relevant fuel yields dependent on
the process conditions. Under stable catalyst conditions, C10 aromatic conversions of more than 60% were obtained, while the CN remained close to that of pure MD. ... mehrHarsh process conditions increased the gasoline yield up to 20% at the cost of MD, while the kerosene yield remained almost constant.
With an optimized lumping model, fuel yields could be predicted with an R2 of 0.998. In this study, co-HP heavy aromatic-rich MTG/DTG fuels with fossil MD were proven to be a promising process strategy compared to a stand-alone after-treatment.