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Group 14 metallole dianions as η$^5$-coordinating ligands

Sun, Xiaofei 1; Roesky, Peter W. 1
1 Institut für Anorganische Chemie (AOC), Karlsruher Institut für Technologie (KIT)

Abstract:

As heavier aromatic analogs of the cyclopentadienides, group 14 dianionic metalloles exhibit more versatile reactivity and coordination modes due to the additional lone pair at the heteroatom. Compared to the well-established chemistry of monoanionic cyclopentadienide ligands, the coordination chemistry with those dianionic ligands remains underexplored. This perspective provides an overview of literature-known examples of group 14 metallole dianions (silole, germole, stannole and plumbole) adopting η$^5$-coordinating modes. The diverse coordination modes and reactivity exhibited by these compounds highlight their potential as intriguing ligands in organometallic chemistry.


Verlagsausgabe §
DOI: 10.5445/IR/1000162595
Veröffentlicht am 28.09.2023
Originalveröffentlichung
DOI: 10.1039/d3qi01342a
Scopus
Zitationen: 5
Web of Science
Zitationen: 5
Dimensions
Zitationen: 7
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Anorganische Chemie (AOC)
Publikationstyp Zeitschriftenaufsatz
Publikationsdatum 26.09.2023
Sprache Englisch
Identifikator ISSN: 2052-1553, 2052-1545
KITopen-ID: 1000162595
Erschienen in Inorganic Chemistry Frontiers
Verlag Royal Society of Chemistry (RSC)
Band 10
Heft 19
Seiten 5509–5516
Nachgewiesen in Scopus
Dimensions
Web of Science
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