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Diverse Reactions of Formazanate/Formazan with Tetrylenes: Reduction, C−H Bond Activation, Substitution and Addition

Jin, Da 1; Sun, Xiaofei 1; Naina, Vanitha R. 1; Roesky, Peter W. 1
1 Institut für Anorganische Chemie (AOC), Karlsruher Institut für Technologie (KIT)

Abstract:

The reactivity of the formazanate potassium salt [L$^{tBu}$K(thf)] (L$^{tBu=}$PhNNC(4-$^t$BuPh)NNPh) with the group 14 chlorotetrylenes [{PhC($^t$BuN)$_2$}ECl] (E=Si, Ge, Sn) was investigated. Three corresponding compounds with unique configurations were formed, demonstrating the diverse reactivity of the system. In addition to the anticipated salt metathesis reactions of the potassium salt with the chlorine function of tetrylenes, unexpected reduction/insertion steps into the N=N bond of the formazanate (Si, Ge) and subsequent C−H activation (Ge) were also observed. Furthermore, when the neutral formazan ligand [L$^{tBu}$H] was exposed to silylenes [{PhC($^t$BuN)$_2$}SiCl] and [L$^{Ph}$SiNMePy], substitution and addition reactions occurred. These discoveries significantly enrich the diversity of formazanate/formazan redox chemistry, opening up new avenues for exploration in this field.


Verlagsausgabe §
DOI: 10.5445/IR/1000162839
Veröffentlicht am 09.10.2023
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Anorganische Chemie (AOC)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2023
Sprache Englisch
Identifikator ISSN: 0947-6539, 1521-3765
KITopen-ID: 1000162839
Erschienen in Chemistry – A European Journal
Verlag John Wiley and Sons
Band 29
Heft 61
Seiten Art.Nr.: e202301958
Bemerkung zur Veröffentlichung This article also appears in:Chemistry of the p-Block Elements,

Chemistry of the p-Block Elements
Vorab online veröffentlicht am 27.09.2023
Schlagwörter bond activation, coordination chemistry, formazanate/formazan, redox reactivity, tetrylenes
Nachgewiesen in Dimensions
Web of Science
Scopus
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