The Solvent‐free Lithium Alanate {Li[$t$‐Bu$_2$AlH$_2$]}$_n$:A New Product Obtained from a Long‐Known Reaction
Abstract:
We report the isolation and characterization of an unknown reaction product from the reaction of AlBr$_3$ with three equivalents of $t$-BuLi. The polymeric and solvent-free lithium alanate {Li[$t$-Bu$_2$AlH$_2$]}$_n$ was characterized by X-ray structure analysis, NMR and IR spectroscopy. The title compound was found to be a suitable starting material for the synthesis of [$t$-Bu$_2$AlH]$_3$ by reacting it with readily available [$t$-Bu$_2$AlBr]$_2$.
| Zugehörige Institution(en) am KIT | Institut für Anorganische Chemie (AOC) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsjahr | 2023 |
| Sprache | Englisch |
| Identifikator | ISSN: 1434-1948, 0009-2940, 0365-947X, 0365-9488, 0365-9496, 1099-0682, 1434-2421, 2749-2567 KITopen-ID: 1000164809 |
| Erschienen in | European Journal of Inorganic Chemistry |
| Verlag | Wiley-VCH Verlag |
| Seiten | Art.-Nr.: e202300561 |
| Vorab online veröffentlicht am | 23.10.2023 |
| Schlagwörter | aluminum, group 13 elements, hydrides, main group chemistry, polymers |
| Nachgewiesen in | Dimensions Scopus Web of Science |