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A Universal Design Strategy Based on NiPS 3 Nanosheets towards Efficient Photothermal Conversion and Solar Desalination

Wang, Honglei; Bo, Yifan; Klingenhof, Malte; Peng, Jiali 1; Wang, Dong; Wu, Bing; Pezoldt, Jörg; Cheng, Pengfei; Knauer, Andrea; Hua, Weibo 1; Wang, Hongguang; van Aken, Peter A.; Sofer, Zdenek; Strasser, Peter; Guldi, Dirk M.; Schaaf, Peter
1 Institut für Angewandte Materialien – Energiespeichersysteme (IAM-ESS), Karlsruher Institut für Technologie (KIT)

Abstract:

2D nanomaterials are proposed as promising photothermal materials for interfacial photothermal water evaporation. However, low evaporation efficiency, the use of hazardous hydrofluoric solution, and poor stability severely limit their practical applications. Here, a mixed solvent exfoliation surface deposition (MSESD) strategy for the preparation of NiPS$_3$ nanosheets and NiPS$_3$/polyvinyl alcohol (PVA) converter is successfully developed. The converter is obtained by drop-casting the NiPS$_3$/PVA nanosheets onto a sponge. The PVA is mainly deposited on the edge of NiPS$_3$ nanosheets, which not only improves the stability of NiPS$_3$ nanosheets, but also adheres to the sponge to prepare a 3D photothermal converter, which shows an evaporation rate of 1.48 kg m$^{−2}$ h$^{−1}$ and the average photothermal conversion efficiency (PTCE) of 93.5% under a light intensity of 1 kW m$^{−2}$. The photothermal conversion mechanism reveals that the energy of absorbed photons in NiPS$_3$ nanosheets can be effectively converted into heat through non-radiative photon transitions as well as multiple optical interactions. To the best of the knowledge, this is the first report on the application of 2D metal-phosphorus-chalcogen (MPChx) for solar desalination, which provides new insights and guidance for the development of high-performance 2D photothermal materials.


Verlagsausgabe §
DOI: 10.5445/IR/1000165032
Veröffentlicht am 28.11.2023
Originalveröffentlichung
DOI: 10.1002/adfm.202310942
Scopus
Zitationen: 10
Web of Science
Zitationen: 1
Dimensions
Zitationen: 12
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Angewandte Materialien – Energiespeichersysteme (IAM-ESS)
Publikationstyp Zeitschriftenaufsatz
Publikationsmonat/-jahr 02.2024
Sprache Englisch
Identifikator ISSN: 1616-301X, 1616-3028
KITopen-ID: 1000165032
Erschienen in Advanced Functional Materials
Verlag Wiley-VCH Verlag
Band 34
Heft 8
Seiten Art.-Nr.:
Vorab online veröffentlicht am 10.11.2023
Schlagwörter 2D materials, desalination, NiPS3 nanosheets, photothermal conversions, surface depositions
Nachgewiesen in Dimensions
Web of Science
Scopus
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