Sound waves, diffusive transport, and wall slip in nanoconfined compressible fluids

Although continuum theories have been proven quite robust to describe confined fluid flow at molecular length scales, molecular dynamics (MD) simulations reveal mechanistic insights into the interfacial dissipation processes. Most MD simulations of confined fluids
have used setups in which the lateral box size is not much larger than the gap height, thus breaking thin-film assumptions usually employed in continuum simulations. Here we explicitly probe the long-wavelength hydrodynamic correlations in confined simple fluids
with MD and compare to gap-averaged continuum theories as typically applied in, e.g., lubrication. Relaxation times obtained from equilibrium fluctuations interpolate between the theoretical limits from bulk hydrodynamics and continuum formulations with increasing
wavelength. We show how to exploit this characteristic transition to measure viscosity and slip length in confined systems simultaneously from equilibrium MD simulations. Moreover, the gap-averaged theory describes a geometry-induced dispersion relation that
leads to overdamped sound relaxation at large wavelengths, which is confirmed by our MD simulations. ... mehrOur results add to the understanding of transport processes under strong confinement and might be of technological relevance for the design of nanofluidic devices.