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Impact of Lithium‐Ion Battery Separators on Gas Evolution during Temperature Abuse

Bläubaum, Lars ORCID iD icon 1; Röse, Philipp ORCID iD icon 1; Baakes, Florian ORCID iD icon 1; Krewer, Ulrike ORCID iD icon 1
1 Institut für Angewandte Materialien – Elektrochemische Technologien (IAM-ET1), Karlsruher Institut für Technologie (KIT)

Abstract:

Separators in lithium-ion batteries are typically considered to be electrochemically inert under normal operating conditions. Yet, temperature abuse tests at elevated temperatures of ca. 60 °C to 132 °C show that the choice of separator material has a decisive influence on battery behavior and degradation. Using online electrochemical mass spectrometry, we analyzed the evolution of cell voltage and gas products during and after thermal abuse for different separators. Polypropylene and polytetrafluoroethylene seem exhibited little change in gas evolution, producing only modest amounts of CO2 and POF3. In contrast, glass fiber and polyethylene terephthalate separators caused additional gas release, indicating electrochemical instability. Polyethylene terephthalate produced significantly more gas, resulting in the mechanical failure of the separator and drastic performance losses. The amount of CO2 evolved with polyethylene terephthalate is four times higher than that of the glass fiber separator. However, the amount of POF3 detected was five times higher for the glass fiber separator.


Verlagsausgabe §
DOI: 10.5445/IR/1000169703
Veröffentlicht am 03.04.2024
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Angewandte Materialien – Elektrochemische Technologien (IAM-ET1)
Publikationstyp Zeitschriftenaufsatz
Publikationsmonat/-jahr 03.2024
Sprache Englisch
Identifikator ISSN: 2566-6223
KITopen-ID: 1000169703
Erschienen in Batteries & Supercaps
Verlag John Wiley and Sons
Band 7
Heft 3
Seiten Art.-Nr. e202300534
Vorab online veröffentlicht am 12.01.2024
Nachgewiesen in Dimensions
Web of Science
Scopus
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