Polymers of Intrinsic Microporosity Containing [2.2]Paracyclophane Moieties: Synthesis and Gas Sorption Properties
Li, Yuting 1; Brückel, Julian 1; Jereb, Marjan; Zupanc, Anže; Hirvonen, Sami-Pekka; Hietala, Sami; Kemell, Marianna; Wu, Yue; Fuhr, Olaf
2; Jansen-van Vuuren, Ross D. ; Carta, Mariolino ; Bräse, Stefan 1
1 Institut für Organische Chemie (IOC), Karlsruher Institut für Technologie (KIT)
2 Institut für Nanotechnologie (INT), Karlsruher Institut für Technologie (KIT)
2; Jansen-van Vuuren, Ross D. ; Carta, Mariolino ; Bräse, Stefan 11 Institut für Organische Chemie (IOC), Karlsruher Institut für Technologie (KIT)
2 Institut für Nanotechnologie (INT), Karlsruher Institut für Technologie (KIT)
Abstract:
The unique structure of [2.2]paracyclophane (PCP) with its rigidity, stability,
and planar chirality has gained significant attention in polymer and material
research. In this work, the incorporation of amino-functionalized PCPs within
polymers of intrinsic microporosity (PIMs) is reported for the first time. Three
different PCP-PIMs were prepared via a Tröger’s base formation mechanism,
and their structures characterized via solid-state NMR, MALDI-TOF, and
SEM. Their porosity was evaluated using gas adsorption (N$_2$ and CO$_2$ ) based
on theoretical calculations such as Brunauer–Emmett–Teller (BET), NLDFT
pore size distribution (PSD) and ideal IAST CO$_2$ /N$_2$ selectivity (15/85), a crucial separation when considering the capture of CO$_2$ from flue gas. The surface areas were found to be between 200–230 m$^2$ g$^{−1}$ while the selectivity
for CO$_2$ /N$_2$ ranged from 46 to 70.
and planar chirality has gained significant attention in polymer and material
research. In this work, the incorporation of amino-functionalized PCPs within
polymers of intrinsic microporosity (PIMs) is reported for the first time. Three
different PCP-PIMs were prepared via a Tröger’s base formation mechanism,
and their structures characterized via solid-state NMR, MALDI-TOF, and
SEM. Their porosity was evaluated using gas adsorption (N$_2$ and CO$_2$ ) based
on theoretical calculations such as Brunauer–Emmett–Teller (BET), NLDFT
pore size distribution (PSD) and ideal IAST CO$_2$ /N$_2$ selectivity (15/85), a crucial separation when considering the capture of CO$_2$ from flue gas. The surface areas were found to be between 200–230 m$^2$ g$^{−1}$ while the selectivity
for CO$_2$ /N$_2$ ranged from 46 to 70.
| Zugehörige Institution(en) am KIT | Institut für Nanotechnologie (INT) Institut für Organische Chemie (IOC) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsmonat/-jahr | 11.2024 |
| Sprache | Englisch |
| Identifikator | ISSN: 1616-301X, 1057-9257, 1099-0712, 1616-3028 KITopen-ID: 1000171712 |
| HGF-Programm | 43.31.01 (POF IV, LK 01) Multifunctionality Molecular Design & Material Architecture |
| Erschienen in | Advanced Functional Materials |
| Verlag | Wiley-VCH Verlag |
| Band | 34 |
| Heft | 47 |
| Seiten | Art.-Nr.: 2401957 |
| Vorab online veröffentlicht am | 25.05.2024 |
| Nachgewiesen in | Dimensions Web of Science Scopus |
| Globale Ziele für nachhaltige Entwicklung |