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Stabilization of P2 layered oxide electrodes in sodium-ion batteries through sodium evaporation

Zarrabeitia, Maider ORCID iD icon 1; Salazar, Iñigo; Acebedo, Begoña; Muñoz-Márquez, Miguel Ángel
1 Helmholtz-Institut Ulm (HIU), Karlsruher Institut für Technologie (KIT)

Abstract:

Sodium-ion batteries are well positioned to become, in the near future, the energy storage system for stationary applications and light electromobility. However, two main drawbacks feed their underperformance, namely the irreversible sodium consumption during solid electrolyte interphase formation and the low sodiation degree of one of the most promising cathode materials: the P2-type layered oxides. Here, we show a scalable and low-cost sodiation process based on sodium thermal evaporation. This method tackles the poor sodiation degree of P2-type sodium layered oxides, thus overcoming the first irreversible capacity as demonstrated by manufacturing and testing all solid-state Na doped-Na~$_1$Mn$_{0.8}$Fe$_{0.1}$Ti$_{0.1}$O$_2$ ǀǀ PEO-based polymer electrolyte ǀǀ Na full cells. The proposed sodium physical vapor deposition method opens the door for an easily scalable and low-cost strategy to incorporate any metal deficiency in the battery materials, further pushing the battery development.


Verlagsausgabe §
DOI: 10.5445/IR/1000173016
Veröffentlicht am 01.08.2024
Cover der Publikation
Zugehörige Institution(en) am KIT Helmholtz-Institut Ulm (HIU)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2024
Sprache Englisch
Identifikator ISSN: 2662-4443
KITopen-ID: 1000173016
HGF-Programm 38.02.01 (POF IV, LK 01) Fundamentals and Materials
Erschienen in Communications Materials
Verlag Springer Nature
Band 5
Heft 1
Seiten Art.-Nr.: 130
Vorab online veröffentlicht am 23.07.2024
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