A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes
Abstract:
We report on the synthesis of an alkane-soluble Zintl cluster, [η4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.
| Zugehörige Institution(en) am KIT | Institut für Nanotechnologie (INT) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsdatum | 28.10.2020 |
| Sprache | Englisch |
| Identifikator | ISSN: 0002-7863, 1520-5126 KITopen-ID: 1000174774 |
| Erschienen in | Journal of the American Chemical Society |
| Verlag | American Chemical Society (ACS) |
| Band | 142 |
| Heft | 43 |
| Seiten | 18330–18335 |
| Vorab online veröffentlicht am | 14.10.2020 |
| Nachgewiesen in | Web of Science Scopus Dimensions |