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Cation‐Dependent Nuclearity of New Homoleptic Azidocuprates(II), From Discrete Ions to Anionic Strands and Sheets

Hinz, Alexander ORCID iD icon 1; Köckerling, Martin
1 Institut für Anorganische Chemie (AOC), Karlsruher Institut für Technologie (KIT)

Abstract:

In chemical reactions of copper(II) acetate dihydrate with imidazolium azide salts in ethanol solution several new homoleptic azidocuprates(II) were obtained. In dependency of the used counter cation various different azidocuprate moieties were crystalized. The doubly charged DMMDIm2+ cation facilitates the formation of mononuclear [Cu(N3)4]2− complex anions, while the utilisation of the (PeMIm)+ ion enables the isolation of a dinuclear [Cu2(N3)6]2− salt. By using the unsymmetrical imidazolium ions (BMIm)+ or (EMIm)+ salts with the trinuclear [Cu3(N3)8]2− complex anion are obtained. With the (DML)+ cation an azidocuprate(II) crystallizes, which contains both [Cu(N3)4]2− and the [Cu2(N3)6]2− anion. The anions in the salt with the (PeMIm)+ cation are interconnected through further Cu−N bonds and form layers with a 2D-honeycomb structure. The trinuclear units in the (BMIm)+ and the (EMIm)+salts form coordination strands of different structures.


Verlagsausgabe §
DOI: 10.5445/IR/1000175733
Veröffentlicht am 29.10.2024
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Anorganische Chemie (AOC)
Publikationstyp Zeitschriftenaufsatz
Publikationsdatum 17.05.2024
Sprache Englisch
Identifikator ISSN: 0044-2313, 1521-3749
KITopen-ID: 1000175733
Erschienen in Zeitschrift für anorganische und allgemeine Chemie
Verlag John Wiley and Sons
Band 650
Heft 9-10
Seiten e202400025
Nachgewiesen in Scopus
Web of Science
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