Isolation of the parent triplet titanocene via NHC stabilisation
Abstract:
We present the synthesis and characterization of the parent isolable monomeric triplet titanocene complex, stabilized by the N-heterocyclic carbene (NHC) IMe4. Investigated by SQUID magnetometry and quantum-chemical calculations, reactivity studies of the titanium precursor [Cp2Ti(btmsa)] (2) with the NHC IiPr2Me2 and the zirconocene complex [Cp2Zr(py)(btmsa)] (1) revealed divergent reactivity patterns, highlighting the role of steric and electronic effects in stabilization.
| Zugehörige Institution(en) am KIT | Institut für Nanotechnologie (INT) |
| Publikationstyp | Zeitschriftenaufsatz |
| Publikationsdatum | 20.05.2025 |
| Sprache | Englisch |
| Identifikator | ISSN: 1477-9226, 0300-9246, 1364-5447, 1470-479X, 1472-7773, 1477-9234, 2050-5671 KITopen-ID: 1000180663 |
| HGF-Programm | 43.31.01 (POF IV, LK 01) Multifunctionality Molecular Design & Material Architecture |
| Erschienen in | Dalton Transactions |
| Verlag | Royal Society of Chemistry (RSC) |
| Band | 54 |
| Heft | 20 |
| Seiten | 8035–8040 |
| Nachgewiesen in | OpenAlex Web of Science Scopus Dimensions |