Implementation of solar UV and energetic particle precipitation within the LINOZ scheme in ICON-ART

We extended the Linearized ozone scheme – LINOZ in the ICON (ICOsahedral Nonhydrostatic) – ART (the extension for Aerosols and Reactive Trace gases) model system to include NOy formed by auroral and medium-energy electrons in the upper mesosphere and lower thermosphere, and the corresponding ozone loss, as well as changes in the rate of ozone formation due to the variability of the solar radiation in the ultraviolet wavelength range. This extension allows us to realistically represent variable solar and geomagnetic forcing in the middle atmosphere using a very simple ozone scheme. The LINOZ scheme is computationally very cheap compared to a full middle atmosphere chemistry scheme, yet provides realistic ozone fields consistent with the stratospheric circulation and temperatures, and can thus be used in climate models instead of prescribed ozone climatologies. To include the reactive nitrogen (NOy) produced by auroral and radiation belt electron precipitation in the upper mesosphere and lower thermosphere during polar winter, the so-called energetic particle precipitation indirect effect, an upper boundary condition for NOy has been implemented into the simplified parameterization scheme of the N2O/NOy reactions. ... mehrThis parameterization, which uses the geomagnetic Ap index, is also recommended for chemistry-climate models in the CMIP6 experiments. With this extension, the model simulates realistic “tongues” of NOy propagating downward in polar witner from the model top in the upper mesosphere into the mid-stratosphere with an amplitude that is modulated by geomagnetic activity. We then expanded the simplified ozone description used in the model by applying LINOZ version 3. The additional ozone tendency from NOy is included by applying the corresponding terms of the version 3 of LINOZ. This NOy, coupled as an additional term in the linearized ozone chemistry, led to significant ozone losses in the polar upper stratosphere in both hemispheres which is qualitatively in good agreement with ozone observations and model simulations with EPP-NOy and full stratospheric chemistry. In a subsequent step, the tabulated coefficients forming the basis of the LINOZ scheme were provided separately for solar maximum and solar minimum conditions. These coefficients were then interpolated to ICON-ART using the F10.7 index as a proxy for daily solar spectra (UV) variability to account for solar UV forcing. This solar UV forcing in the model led to changes in ozone in the tropical and mid-latitude stratosphere consistent with observed solar signals in stratospheric ozone.