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Soft Mode Origin of Charge Ordering in Superconducting Kagome CsV$_3$Sb$_5$

McGuinness, Philippa Helen; Henssler, Fabian ORCID iD icon 1; Alkorta, Manex; von Westarp, Mark Joachim Graf 1; Korshunov, Artem; Bosak, Alexei; Ishikawa, Daisuke; Baron, Alfred Q. R.; Merz, Michael 1; Haghighirad, Amir-Abbas 1; Vergniory, Maia G.; Souliou, Sofia-Michaela 1; Heid, Rolf 1; Errea, Ion; Tacon, Matthieu Le ORCID iD icon 1
1 Institut für QuantenMaterialien und Technologien (IQMT), Karlsruher Institut für Technologie (KIT)

Abstract:

Charge-density-wave (CDW) order and superconductivity coexist in the kagome metals AV$_3$Sb$_5$ (A=K, Cs, Rb), raising fundamental questions about the mechanisms driving their intertwined phases. Here we combine high-resolution inelastic X-ray scattering with first-principles calculations to uncover the origin of CDW formation in CsV$_3$Sb$_5$. Guided by structure factor analysis, we identify a soft phonon mode along the reciprocal M-L direction, with the strongest effect at the L point, where the elastic scattering intensity also grows most rapidly upon cooling. First-principles calculations incorporating lattice anharmonicity and electron-phonon coupling reproduce these observations and establish a soft-mode instability at the L point as the driving mechanism of CDW formation. Despite the weakly first-order character of the transition, our results unambiguously demonstrate that the CDW in CsV$_3$Sb$_5$ originates from a softened phonon, clarifying its microscopic origin and highlighting the central role of lattice dynamics in kagome metals.


Volltext §
DOI: 10.5445/IR/1000189760
Veröffentlicht am 20.01.2026
Originalveröffentlichung
DOI: 10.48550/arXiv.2510.19790
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für QuantenMaterialien und Technologien (IQMT)
Publikationstyp Forschungsbericht/Preprint
Publikationsdatum 22.10.2025
Sprache Englisch
Identifikator KITopen-ID: 1000189760
HGF-Programm 47.11.02 (POF IV, LK 01) Emergent Quantum Phenomena
Verlag arxiv
Umfang 25 S.
Schlagwörter Superconductivity (cond-mat.supr-con), Strongly Correlated Electrons (cond-mat.str-el)
Nachgewiesen in OpenAlex
arXiv
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