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URN: urn:nbn:de:swb:90-421069

Industrially Relevant Monomers: From Fundamental Kinetics to Application in Controlled Polymerization

Hähnel, Alexander Peter

Arrhenius parameters of the propagation rate coefficient, kp, of (meth)acrylates are determined (via PLP-SEC) in order to detect global structure-property relationships. Additional physicochemical data is employed in providing a plausible reasoning for the identified trends. The reported kp values are of highest importance for kinetic modeling also of RDRP processes such as ATRP or RAFT. Furthermore, MHKS parameters, temperature dependent densities, viscosities, Tg and dn/dc values are reported.

Zugehörige Institution(en) am KIT Institut für Technische Chemie und Polymerchemie (ITCP)
Publikationstyp Hochschulschrift
Jahr 2014
Sprache Englisch
Identifikator KITopen-ID: 1000042106
Verlag Karlsruhe
Abschlussart Dissertation
Fakultät Fakultät für Chemie und Biowissenschaften (CHEM-BIO)
Institut Institut für Technische Chemie und Polymerchemie (ITCP)
Prüfungsdaten 18.07.2014
Referent/Betreuer Prof. C. Barner-Kowollik
Schlagworte Pulsed Laser Polymerization, Size Exclusion Chromatography (PLP-SEC), Propagation Rate Coefficient kp, Free Radical Polymerization (FRP), kinetics
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