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Highly efficient polymer solar cells cast from non-halogenated xylene/anisaldehyde solution

Sprau, C.; Buss, F.; Wagner, M.; Landerer, D.; Koppitz, M.; Schulz, A.; Bahro, D.; Schabel, W.; Scharfer, P.; Colsmann, A.

Abstract:
Several high performance polymer:fullerene bulk-heterojunction photo-active layers, deposited from the non-halogenated solvents o-xylene or anisole in combination with the eco-compatible additive p-anisaldehyde, are investigated. The respective solar cells yield excellent power conversion efficiencies up to 9.5%, outperforming reference devices deposited from the commonly used halogenated chlorobenzene/1,8-diiodooctane solvent/additive combination. The impact of the processing solvent on the bulk-heterojunction properties is exemplified on solar cells comprising benzodithiophene-thienothiophene co-polymers and functionalized fullerenes (PTB7:PC71BM). The additive p-anisaldehyde improves film formation, enhances polymer order, reduces fullerene agglomeration and shows high volatility, thereby positively affecting layer deposition, improving charge carrier extraction and reducing drying time, the latter being crucial for future large area roll-to-roll device fabrication. © The Royal Society of Chemistry 2015.

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Volltext §
DOI: 10.5445/IR/1000050693
Originalveröffentlichung
DOI: 10.1039/c5ee01917f
Scopus
Zitationen: 85
Web of Science
Zitationen: 86
Coverbild
Zugehörige Institution(en) am KIT Institut für Thermische Verfahrenstechnik (TVT)
Lichttechnisches Institut (LTI)
Publikationstyp Zeitschriftenaufsatz
Jahr 2015
Sprache Englisch
Identifikator ISSN: 1754-5692
urn:nbn:de:swb:90-506936
KITopen-ID: 1000050693
HGF-Programm 43.22.03 (POF III, LK 01)
Erschienen in Energy and Environmental Science
Band 8
Heft 9
Seiten 2744-2752
Bemerkung zur Veröffentlichung RSC geförderter Open Access-Artikel
Nachgewiesen in Scopus
Web of Science
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