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Novel Approaches Towards Sequence-Defined Macromolecules using Isocyanide-Based Multicomponent Reactions

Solleder, Susanne Carina



Abstract (englisch): This thesis describes novel approaches for the synthesis of sequence-defined macromolecules by the use of multicomponent reactions. First, a protecting group-free approach was investigated making use of the Passerini (P-3CR) and the Ugi reaction. Then, monomers for the P-3CR were synthesized and used for the synthesis of a decamer. Moreover, a convergent synthesis approach was investigated and macromolecules were synthesized by combination of the P-3CR and thiolactone chemistry.


Zugehörige Institution(en) am KIT Institut für Organische Chemie (IOC)
Publikationstyp Hochschulschrift
Jahr 2016
Sprache Englisch
Identifikator DOI(KIT): 10.5445/IR/1000057696
URN: urn:nbn:de:swb:90-576961
KITopen ID: 1000057696
Umfang IV, 304 S.
Abschlussart Dissertation
Fakultät Fakultät für Chemie und Biowissenschaften (CHEM-BIO)
Prüfungsdaten 22.07.2016
Referent/Betreuer Prof. M. A. R. Meier
Schlagworte Sequence-control; Multicomponent Reactions; Passerini Reaction; monodisperse
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