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Optimal Control-Enhanced Deconvolution of NMR Spectra: Homo- and Heteronuclear Decoupling

Reinsperger, Tony

Abstract (englisch):
The present thesis reports new approaches to increase sensitivity and resolution in high-resolution NMR spectroscopy via homo- and heteronuclear decoupling. First, a methodology to obtain a new class of self-compensating heteronuclear decoupling sequences by means of numerical optimizations based on optimal control algorithms is presented. Further, the pure shift methodology is applied to heteronuclear correlation experiments in order to measure heteronuclear one-bond couplings more accurately.


Zugehörige Institution(en) am KIT Institut für Biologische Grenzflächen (IBG)
Publikationstyp Hochschulschrift
Jahr 2016
Sprache Englisch
Identifikator DOI(KIT): 10.5445/IR/1000058181
URN: urn:nbn:de:swb:90-581811
KITopen ID: 1000058181
Verlag Karlsruhe
Umfang VI, 268 S,
Abschlussart Dissertation
Fakultät Fakultät für Chemie und Biowissenschaften (CHEM-BIO)
Institut Institut für Biologische Grenzflächen (IBG)
Prüfungsdaten 22.07.2016
Referent/Betreuer Prof. B. Luy
Schlagworte NMR Spectroscopy, Optimal Control Theory, Heteronuclear Decoupling Sequences, Pure Shift NMR, Residual Dipolar Couplings
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