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Synthesis of novel bisphosphorylimides based on Staudinger reaction

Weber, L.; Weinert, M.; Goedderz, D.; Fuhr, O.; Döring, M.

Abstract:
A series of bisphosphorylimides based on the reaction sequence of Atherton-Todd and Staudinger reaction were synthesized. These bisphosphorylimides containing phosphorus in different chemical environments, while the reaction sequence is using mild conditions and moreover can be synthesized in an one-pot procedure. The molecular structures were revealed by nuclear magnetic resonance spectroscopy and x-ray crystallography. The stability of the bisphosphorylimides against hydrolysis and thermal influences was tested which allows an initial estimation about the usage as flame retardant.

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Verlagsausgabe §
DOI: 10.5445/IR/1000124113
Veröffentlicht am 19.10.2020
Originalveröffentlichung
DOI: 10.24820/ARK.5550190.P011.150dummy2
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Nanotechnologie (INT)
Karlsruhe Nano Micro Facility (KNMF)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2020
Sprache Englisch
Identifikator ISSN: 1424-6369, 1551-7004, 1551-7012
KITopen-ID: 1000124113
Erschienen in Arkivoc
Band 2020
Heft 6
Seiten Art. Nr.: A25
Vorab online veröffentlicht am 05.04.2020
Schlagwörter 9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, phosphorus, bisphosphorylimides, Staudinger reaction, Atherton-Todd reaction
Nachgewiesen in Scopus
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