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Advancing Inorganic Coordination Chemistry by Spectroscopy of Isolated Molecules: Methods and Applications

Niedner-Schatteburg, Gereon; Kappes, Manfred M.


A unique feature of the work carried out in the Collaborative Research Center 3MET continues to be its emphasis on innovative, advanced experimental methods which hyphenate mass-selection with further analytical tools such as laser spectroscopy for the study of isolated molecular ions. This allows to probe the intrinsic properties of the species of interest free of perturbing solvent or matrix effects. This review explains these methods and uses examples from past and ongoing 3MET studies of specific classes of multicenter metal complexes to illustrate how coordination chemistry can be advanced by applying them. As a corollary, we will show how the challenges involved in providing well-defined, for example monoisomeric, samples of the molecular ions have helped to further improve the methods themselves thus also making them applicable to many other areas of chemistry.

Verlagsausgabe §
DOI: 10.5445/IR/1000141353
Veröffentlicht am 18.12.2021
DOI: 10.1002/chem.202102815
Zitationen: 1
Web of Science
Zitationen: 3
Zitationen: 3
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Nanotechnologie (INT)
Institut für Physikalische Chemie (IPC)
Publikationstyp Zeitschriftenaufsatz
Publikationsmonat/-jahr 11.2021
Sprache Englisch
Identifikator ISSN: 0947-6539, 1521-3765
KITopen-ID: 1000141353
HGF-Programm 43.31.01 (POF IV, LK 01) Multifunctionality Molecular Design & Material Architecture
Erschienen in Chemistry - a European journal
Verlag John Wiley and Sons
Band 27
Heft 61
Seiten 15028–15043
Vorab online veröffentlicht am 27.10.2021
Nachgewiesen in Scopus
Web of Science
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