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Enhancing Flow Batteries: Topology Optimization of Electrode Porosity and Shape Optimization of Cell Design

Wolf, Amadeus 1; Noack, Jens; Krause, Mathias J. 2; Nirschl, Hermann 1
1 Institut für Mechanische Verfahrenstechnik und Mechanik (MVM), Karlsruher Institut für Technologie (KIT)
2 Karlsruher Institut für Technologie (KIT)

Abstract:

This research focuses on the improvement of porosity distribution within the electrode of an all-vanadium redox flow battery (VRFB) and on optimizing novel cell designs. A half-cell model, coupled with topology and shape optimization framework, is introduced. The multiobjective functional in both cases aims to minimize pressure drop while maximizing reaction rate within the cell. Topology optimization results reveal dependencies on initial value, porosity constraint, and flow rate. The distribution with lower porosity is preferred downstream of the inlet manifold. This design enhances active surface area, thus facilitating more effective conversion of incoming educts and improving mass transport of products. Compared to homogeneous electrodes, two-part design demonstrates superior performance at specific porosity values. For combined porosities of 0.7 and 0.95, optimized distribution results in 81 % reduction in pressure drop, while conversion rate decreases by 7%. As regards various cell designs, optimization suggests a need to reconsider the vertical format of a rectangular cell. Horizontal cells are favored for nearly all porosities and flow rates. ... mehr


Verlagsausgabe §
DOI: 10.5445/IR/1000171701
Veröffentlicht am 17.06.2024
Cover der Publikation
Zugehörige Institution(en) am KIT Institut für Mechanische Verfahrenstechnik und Mechanik (MVM)
Publikationstyp Zeitschriftenaufsatz
Publikationsjahr 2024
Sprache Englisch
Identifikator ISSN: 2194-4288, 2194-4296
KITopen-ID: 1000171701
Erschienen in Energy Technology
Verlag Wiley-VCH Verlag
Band 12
Heft 7
Seiten Art.-Nr.: 2400244
Vorab online veröffentlicht am 25.05.2024
Nachgewiesen in Web of Science
Dimensions
Scopus
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